In Situ Generation of Diimide from Hydrazine and Oxygen: Continuous‐Flow Transfer Hydrogenation of Olefins | Zendy

Pieber Bartholomäus | Zendy; Martinez Sabrina Teixeira | Zendy; Cantillo David | Zendy; Kappe C. Oliver | Zendy

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In Situ Generation of Diimide from Hydrazine and Oxygen: Continuous‐Flow Transfer Hydrogenation of Olefins

Author(s) -

Pieber Bartholomäus,

Martinez Sabrina Teixeira,

Cantillo David,

Kappe C. Oliver

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303528

Subject(s) - hydrazine (antidepressant) , diimide , catalysis , computer science , in situ , process (computing) , chemistry , process engineering , combinatorial chemistry , materials science , organic chemistry , operating system , molecule , engineering , perylene , chromatography

No catalyst required! A highly efficient, catalyst‐free process to generate diimide in situ from hydrazine monohydrate and molecular oxygen for the selective reduction of alkenes has been developed. The use of a gas–liquid segmented flow system allowed safe operating conditions and dramatically enhanced this atom‐economical reaction, resulting in short processing times.

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