Metal‐Free HB(C 6 F 5 ) 2 ‐Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane‐Mediated σ‐Bond Metathesis | Zendy

Wang Yuwen | Zendy; Chen Weiqiang | Zendy; Lu Zhenpin | Zendy; Li Zhen Hua | Zendy; Wang Huadong | Zendy

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Metal‐Free HB(C 6 F 5 ) 2 ‐Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane‐Mediated σ‐Bond Metathesis

Author(s) -

Wang Yuwen,

Chen Weiqiang,

Lu Zhenpin,

Li Zhen Hua,

Wang Huadong

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303500

Subject(s) - borane , metathesis , catalysis , olefin metathesis , chemistry , metal , salt metathesis reaction , organic chemistry , combinatorial chemistry , polymerization , polymer

Out with the metal : Metal‐free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C 6 F 5 ) 2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane‐mediated σ‐bond metathesis, which has been investigated both experimentally and theoretically.

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