A Mild, One‐Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous‐Flow | Zendy

Wang Xiao | Zendy; Cuny Gregory D. | Zendy; Noël Timothy | Zendy

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A Mild, One‐Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous‐Flow

Author(s) -

Wang Xiao,

Cuny Gregory D.,

Noël Timothy

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303483

Subject(s) - microreactor , photoredox catalysis , aryl , catalysis , continuous flow , alkyl , chemistry , visible spectrum , combinatorial chemistry , organic chemistry , photochemistry , chemical engineering , materials science , photocatalysis , biochemical engineering , engineering , optoelectronics

Visible advance : A mild, one‐pot Stadler–Ziegler process for CS bond formation has been developed. The method employs the photoredox catalyst [Ru(bpy) 3 Cl 2 ]⋅6 H 2 O irradiated with visible light. A variety of aryl–alkyl and diaryl sulfides were prepared from readily available arylamines and aryl/alkylthiols in good yields. The use of a photo microreactor led to a significant improvement with respect to safety and efficiency.

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