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Direct syn Insertion of Alkynes and Allenes into AuSi Bonds
Author(s) -
Joost Maximilian,
Gualco Pauline,
MalletLadeira Sonia,
Amgoune Abderrahmane,
Bourissou Didier
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303450
Subject(s) - computer science , insert (composites) , service (business) , chemistry , materials science , business , composite material , marketing
Complete control : Alkynes and allenes are shown to insert into AuSi bonds with complete stereocontrol and in most cases complete regiocontrol. The ensuing β‐silyl vinylgold complexes have been characterized by spectroscopic and crystallographic means. These results provide unequivocal evidence for syn insertion reactions at gold.