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A Resol‐Assisted Co‐Assembly Approach to Crystalline Mesoporous Niobia Spheres for Electrochemical Biosensing
Author(s) -
Luo Wei,
Li Yuhui,
Dong Junping,
Wei Jing,
Xu Jiaqiang,
Deng Yonghui,
Zhao Dongyuan
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303353
Subject(s) - mesoporous material , materials science , nanocrystalline material , nanotechnology , self assembly , electrochemistry , chemical engineering , copolymer , amphiphile , evaporation , solvent , hexagonal crystal system , spheres , nanostructure , catalysis , chemistry , organic chemistry , electrode , crystallography , polymer , composite material , physics , engineering , thermodynamics , astronomy
Templated pores : A resol‐assisted solvent‐evaporation‐induced self‐assembly (RA‐EISA) gives unique ordered mesoporous niobia spheres by using the amphiphilic diblock copolymer PEO‐ b ‐PS as a template. The mesoporous Nb 2 O 5 spheres have ordered hexagonal structures, large pore size and high surface area, and a nanocrystalline framework (see picture). They show excellent electrochemical sensing of hydrogen peroxide.
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