Trifluoromethylation Reactions for the Synthesis of β‐Trifluoromethylamines | Zendy

Egami Hiromichi | Zendy; Kawamura Shintaro | Zendy; Miyazaki Ayako | Zendy; Sodeoka Mikiko | Zendy

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Trifluoromethylation Reactions for the Synthesis of β‐Trifluoromethylamines

Author(s) -

Egami Hiromichi,

Kawamura Shintaro,

Miyazaki Ayako,

Sodeoka Mikiko

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303350

Subject(s) - trifluoromethylation , reagent , chemistry , component (thermodynamics) , combinatorial chemistry , scheme (mathematics) , variety (cybernetics) , organic chemistry , computer science , mathematics , trifluoromethyl , physics , mathematical analysis , alkyl , artificial intelligence , thermodynamics

A multitalented system : N ‐Migratory oxytrifluoromethylation and one‐pot three‐component reactions of allylamines as well as the aminotrifluoromethylation of alkenyl amines all proceeded efficiently in the presence of the Togni reagent ( 1 ) and CuI to afford a variety of β‐trifluoromethylamine derivatives (see scheme).

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