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Total Synthesis of Indotertine A and Drimentines A, F, and G
Author(s) -
Sun Yu,
Li Ruofan,
Zhang Wenhao,
Li Ang
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303334
Subject(s) - key (lock) , iminium , computer science , service (business) , information retrieval , chemistry , world wide web , organic chemistry , business , computer security , marketing , catalysis
Oh my darling, Drimentine : The first total synthesis of the pyrroloindoline alkaloids drimentines A, F, and G, and their congener, indotertine A, is reported. An intermolecular radical conjugate addition was key in the synthesis of the drimentine alkaloids, and a biologically inspired iminium–olefin cyclization converted drimentine F into indotertine A.