Addressing Challenges in Palladium‐Catalyzed Cross‐Couplings of Aryl Mesylates: Monoarylation of Ketones and Primary Alkyl Amines | Zendy

Alsabeh Pamela G. | Zendy; Stradiotto Mark | Zendy

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Addressing Challenges in Palladium‐Catalyzed Cross‐Couplings of Aryl Mesylates: Monoarylation of Ketones and Primary Alkyl Amines

Author(s) -

Alsabeh Pamela G.,

Stradiotto Mark

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303305

Subject(s) - aryl , methylamine , primary (astronomy) , amine gas treating , alkyl , ketone , chemistry , catalysis , combinatorial chemistry , palladium , organic chemistry , computer science , database , physics , astronomy

Mor(DalPhos) for Me(sylates) : Described are the first examples of ketone mono‐α‐arylation and primary aliphatic amine monoarylation employing aryl methanesulfonate coupling partners. A range of functionalized aryl mesylates were employed with dialkyl ketones, and also with primary and secondary amines as well as the otherwise challenging coupling partners acetone and methylamine. Ad=adamantyl.

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