Reversible Switching of the Luminescence of a Photoresponsive Gadolinium(III) Complex | Zendy

Nakai Hidetaka | Zendy; Kitagawa Kazuhiro | Zendy; Nakamori Harutaka | Zendy; Tokunaga Taisuke | Zendy; Matsumoto Takahiro | Zendy; Nozaki Koichi | Zendy; Ogo Seiji | Zendy

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Reversible Switching of the Luminescence of a Photoresponsive Gadolinium(III) Complex

Author(s) -

Nakai Hidetaka,

Kitagawa Kazuhiro,

Nakamori Harutaka,

Tokunaga Taisuke,

Matsumoto Takahiro,

Nozaki Koichi,

Ogo Seiji

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303137

Subject(s) - luminescence , gadolinium , phosphorescence , computer science , key (lock) , photochemistry , chemistry , materials science , optoelectronics , optics , physics , computer security , organic chemistry , fluorescence

From blue to red : The structure and luminescence properties of the gadolinium(III) complex 1 were investigated. Reversible switching of the luminescence of 1 in THF at room temperature by alternating light irradiation and O 2 exposure is presented, during which the emission color changes as shown in the picture. Light‐induced phosphorescence of 1 plays a key role in this behavior.

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