Templated Hierarchical Self‐Assembly of Poly( p ‐aryltriazole) Foldamers | Zendy

Pfukwa Rueben | Zendy; Kouwer Paul H. J. | Zendy; Rowan Alan E. | Zendy; Klumperman Bert | Zendy

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Templated Hierarchical Self‐Assembly of Poly( p ‐aryltriazole) Foldamers

Author(s) -

Pfukwa Rueben,

Kouwer Paul H. J.,

Rowan Alan E.,

Klumperman Bert

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303135

Subject(s) - solvophobic , foldamer , self assembly , folding (dsp implementation) , chirality (physics) , nanotechnology , chemistry , materials science , crystallography , organic chemistry , physics , molecule , chiral symmetry breaking , engineering , quantum mechanics , quark , nambu–jona lasinio model , electrical engineering

A biomimetic approach has been used for the templated self‐assembly of a helical poly( para ‐aryltriazole) foldamer. The solvophobic folding process yields helices that further self‐assemble into long nanotubes (see picture; scale bar: 100 nm). Constructs of controlled length and chirality can be generated by applying a poly( γ ‐benzyl‐l‐glutamate) scaffold at the appropriate assembly conditions, mimicking tobacco mosaic virus self‐assembly.

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