Exceptional Poly(acrylic acid)‐Based Artificial [FeFe]‐Hydrogenases for Photocatalytic H 2  Production in Water | Zendy

Wang Feng | Zendy; Liang WenJing | Zendy; Jian JingXin | Zendy; Li ChengBo | Zendy; Chen Bin | Zendy; Tung ChenHo | Zendy; Wu LiZhu | Zendy

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Exceptional Poly(acrylic acid)‐Based Artificial [FeFe]‐Hydrogenases for Photocatalytic H 2 Production in Water

Author(s) -

Wang Feng,

Liang WenJing,

Jian JingXin,

Li ChengBo,

Chen Bin,

Tung ChenHo,

Wu LiZhu

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303110

Subject(s) - hydrogenase , photocatalysis , acrylic acid , ascorbic acid , catalysis , production (economics) , chemistry , computer science , polymer , nanotechnology , combinatorial chemistry , materials science , food science , biochemistry , organic chemistry , copolymer , economics , macroeconomics

Light, polymer, action : A set of water‐soluble poly(acrylic acid) catalysts PAA‐ g ‐Fe 2 S 2 containing {Fe 2 S 2 }, an [FeFe]‐hydrogenase active‐site mimic, is synthesized. This system, combined with CdSe quantum dots and ascorbic acid, has an exceptional turnover number and initial turnover frequency (27 135 and 3.6 s −1 ) for the photocatalytic production of H 2 in water, which is the highest efficiency to date for [FeFe]‐hydrogenase mimics.

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