Palladium(II)‐Catalyzed Dehydrogenative Cross‐Coupling between Two C       sp       3      H Bonds: Unexpected CC Bond Formation | Zendy

Li Gaocan | Zendy; Qian Shengyou | Zendy; Wang Chunxia | Zendy; You Jingsong | Zendy

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Palladium(II)‐Catalyzed Dehydrogenative Cross‐Coupling between Two C sp 3 H Bonds: Unexpected CC Bond Formation

Author(s) -

Li Gaocan,

Qian Shengyou,

Wang Chunxia,

You Jingsong

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303099

Subject(s) - palladium , bond , catalysis , chemistry , coupling (piping) , benzofuran , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , business , materials science , metallurgy , finance

CC bond construction : A palladium‐catalyzed oxidative C sp 3H/C sp 3H cross‐coupling is shown to forge CC bonds rather than C sp 3C sp 3bonds through reactions of indolin‐2‐ones or benzofuran‐2‐ones with O ‐benzoyl hydroxylamines in the absence of an added oxidant.

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