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Palladium(II)‐Catalyzed Dehydrogenative Cross‐Coupling between Two C sp 3 H Bonds: Unexpected CC Bond Formation
Author(s) -
Li Gaocan,
Qian Shengyou,
Wang Chunxia,
You Jingsong
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303099
Subject(s) - palladium , bond , catalysis , chemistry , coupling (piping) , benzofuran , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , business , materials science , metallurgy , finance
CC bond construction : A palladium‐catalyzed oxidative C sp 3H/C sp 3H cross‐coupling is shown to forge CC bonds rather than C sp 3C sp 3bonds through reactions of indolin‐2‐ones or benzofuran‐2‐ones with O ‐benzoyl hydroxylamines in the absence of an added oxidant.