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Stepwise‐Resolved Thermodynamics of Hydrophobic Self‐Assembly
Author(s) -
Grego Alina,
Müller Achim,
Weinstock Ira A.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303083
Subject(s) - aggregate (composite) , chemistry , computer science , nanotechnology , materials science
Unprecedented information concerning how the relative roles of different hydrophobic effects evolve during multistep hydrophobic assembly processes is provided by using a unique type of experiment to resolve the underlying energetics of individual growth steps in the formation of a structurally well‐defined micelle‐like organic aggregate of n ‐butyrate ions within a porous inorganic‐oxide nanocapsule.
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