Protecting‐Group‐Free Total Synthesis of (−)‐Rhazinilam and (−)‐Rhazinicine using a Gold‐Catalyzed Cascade Cyclization | Zendy

Sugimoto Kenji | Zendy; Toyoshima Kazuki | Zendy; aka Shiori | Zendy; Kotaki Kenta | Zendy; Ueda Hirofumi | Zendy; Tokuyama Hidetoshi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Protecting‐Group‐Free Total Synthesis of (−)‐Rhazinilam and (−)‐Rhazinicine using a Gold‐Catalyzed Cascade Cyclization

Author(s) -

Sugimoto Kenji,

Toyoshima Kazuki,

aka Shiori,

Kotaki Kenta,

Ueda Hirofumi,

Tokuyama Hidetoshi

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303067

Subject(s) - scope (computer science) , generality , cascade , total synthesis , computer science , production (economics) , database , chemistry , stereochemistry , programming language , psychology , chromatography , psychotherapist , economics , macroeconomics

‘Rhaz'zmatazz : A total synthesis of (−)‐rhazinilam and the first asymmetric total synthesis of (−)‐rhazinicine were accomplished by using constructing the indolizinone core through the gold‐catalyzed cyclization of a fully elaborated linear ynamide. The scope and generality of this cascade reaction for the construction of highly substituted indolizinones were also investigated.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research