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Inside Cover: Synthesis and Application of β‐Substituted Pauson–Khand Adducts: Trifluoromethyl as a Removable Steering Group (Angew. Chem. Int. Ed. 20/2013)
Author(s) -
Aiguabella Nuria,
del Pozo Carlos,
Verdaguer Xavier,
Fustero Santos,
Riera Antoni
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303054
Subject(s) - trifluoromethyl , int , cover (algebra) , adduct , group (periodic table) , chemistry , pauson–khand reaction , medicinal chemistry , stereochemistry , organic chemistry , computer science , engineering , catalysis , mechanical engineering , programming language , alkyl
Full steam ahead to β‐substituted Pauson–Khand adducts: By using the trifluoromethyl group as a removable steering group, A. Riera and co‐workers synthesized the previously unknown regioisomers of the Pauson–Khand reaction of terminal alkynes, as they describe in their Communication on page 5355 ff The synthetic potential of the new adducts has been shown by a short formal synthesis of α‐cuparenone (artwork by Pau Martin Malpartida from a picture of Leo Reynolds).