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An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions
Author(s) -
Fischer Sabrina,
Schmidt Johannes,
Strauch Peter,
Thomas Arne
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303045
Subject(s) - microporous material , polymerization , polymer , zeolite , covalent bond , polymer science , computer science , chemistry , nanotechnology , materials science , polymer chemistry , chemical engineering , organic chemistry , engineering , catalysis
Organic zeolite : A microporous, covalent organic network with high surface area was synthesized by polymerization of [B(C 6 F 4 Br) 4 ] − . The countercations, located within the pore channels, are highly accessible and can be easily exchanged, comparable to the extra‐framework cations in zeolites. In this way a [Mn II (bpy)] 2+ complex can be synthesized and immobilized in the network.