An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions | Zendy

Fischer Sabrina | Zendy; Schmidt Johannes | Zendy; Strauch Peter | Zendy; Thomas Arne | Zendy

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An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions

Author(s) -

Fischer Sabrina,

Schmidt Johannes,

Strauch Peter,

Thomas Arne

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303045

Subject(s) - microporous material , polymerization , polymer , zeolite , covalent bond , polymer science , computer science , chemistry , nanotechnology , materials science , polymer chemistry , chemical engineering , organic chemistry , engineering , catalysis

Organic zeolite : A microporous, covalent organic network with high surface area was synthesized by polymerization of [B(C 6 F 4 Br) 4 ] − . The countercations, located within the pore channels, are highly accessible and can be easily exchanged, comparable to the extra‐framework cations in zeolites. In this way a [Mn II (bpy)] 2+ complex can be synthesized and immobilized in the network.

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