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Palladium‐Induced Pyrrolic Rearrangement of a Singly to a Doubly N‐Confused [26]Hexaphyrin
Author(s) -
Gokulnath Sabapathi,
Nishimura Keiichi,
Toganoh Motoki,
Mori Shigeki,
Furuta Hiroyuki
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302955
Subject(s) - palladium , chemistry , metalation , medicinal chemistry , photochemistry , stereochemistry , catalysis , organic chemistry
A pyrrolic rearrangement reaction of singly N‐confused [26]hexaphyrin mediated by PdCl 2 afforded doubly N‐confused [26]hexaphyrin bis(Pd II ) complex. The bis(Pd II ) complex is a rare example of an aromatic compound with definite non‐degenerate HOMOs and LUMOs.