Ultrathin Nanosheets of Half‐Metallic Monoclinic Vanadium Dioxide with a Thermally Induced Phase Transition | Zendy

Yao Tao | Zendy; Liu Liang | Zendy; Xiao Chong | Zendy; Zhang Xiaodong | Zendy; Liu Qinghua | Zendy; Wei Shiqiang | Zendy; Xie Yi | Zendy

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Ultrathin Nanosheets of Half‐Metallic Monoclinic Vanadium Dioxide with a Thermally Induced Phase Transition

Author(s) -

Yao Tao,

Liu Liang,

Xiao Chong,

Zhang Xiaodong,

Liu Qinghua,

Wei Shiqiang,

Xie Yi

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201302891

Subject(s) - monoclinic crystal system , vanadium dioxide , spintronics , phase (matter) , phase transition , materials science , nanotechnology , intercalation (chemistry) , transition metal , vanadium , crystallography , condensed matter physics , chemistry , inorganic chemistry , crystal structure , metallurgy , physics , thin film , ferromagnetism , organic chemistry , catalysis , biochemistry

Only the half of it : A modified intercalation–deintercalation strategy that takes advantage of the characteristic thermally induced phase transition of monoclinic VO 2 has been developed for the preparation of ultrathin VO 2 nanosheets. The resultant nanosheets exhibit half‐metallic character and a temperature‐dependent phase transition. The half‐metallicity could lead to applications in spintronic nanodevices.

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