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Direct CH Amination of Arenes with Alkyl Azides under Rhodium Catalysis
Author(s) -
Shin Kwangmin,
Baek Yunjung,
Chang Sukbok
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302784
Subject(s) - amination , alkyl , rhodium , chemistry , catalysis , combinatorial chemistry , organic chemistry , functional group , polymer
New horizons in the utility of azides : The rhodium‐catalyzed intermolecular direct CH amination of arenes with alkyl azides provides a convenient route to N ‐alkyl anilines (see scheme; DG=directing group). Alkyl azides with a wide range of functional groups reacted readily with various substrates, including benzamides, aromatic ketones, and flavones.