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Facile Monolayer Formation on SiO 2 Surfaces via Organoboron Functionalities
Author(s) -
Agarwala Arunava,
Subramani Thangavel,
Goldbourt Amir,
Danovich David,
Yerushalmi Roie
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302655
Subject(s) - organoboron compounds , monolayer , reactivity (psychology) , boron , chemistry , materials science , surface modification , nanoparticle , chemical engineering , nanotechnology , organic chemistry , pathology , engineering , medicine , alternative medicine
More than they appear on the surface : The treatment of SiO 2 nanoparticles under mild conditions with two organoboron derivatives led to boron‐containing monolayers with different types of surface species (see picture) through the direct formation of SiOB bonds. The organoboron‐modified SiO 2 NPs showed selective reactivity towards diols.