Quasi‐Solid‐State Rechargeable Lithium‐Ion Batteries with a Calix[4]quinone Cathode and Gel Polymer Electrolyte | Zendy

Huang Weiwei | Zendy; Zhu Zhiqiang | Zendy; Wang Lijiang | Zendy; Wang Shiwen | Zendy; Li Hao | Zendy; Tao Zhanliang | Zendy; Shi Jifu | Zendy; Guan Lunhui | Zendy; Chen Jun | Zendy

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Quasi‐Solid‐State Rechargeable Lithium‐Ion Batteries with a Calix[4]quinone Cathode and Gel Polymer Electrolyte

Author(s) -

Huang Weiwei,

Zhu Zhiqiang,

Wang Lijiang,

Wang Shiwen,

Li Hao,

Tao Zhanliang,

Shi Jifu,

Guan Lunhui,

Chen Jun

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201302586

Subject(s) - lithium (medication) , electrolyte , quinone , acrylate , polymer , cathode , ion , ethylene glycol , anode , materials science , chemical engineering , chemistry , electrode , organic chemistry , copolymer , engineering , medicine , endocrinology

Filled to capacity : Calix[4]quinone (C4Q) has eight available carbonyl groups for binding lithium ions (see picture). It can be exploited to prepare quasi‐solid‐state rechargeable lithium batteries with a poly(methyl acrylate)/poly(ethylene glycol) based gel polymer electrolyte and a LiClO 4 /DMSO loading. It shows an initial discharge capacity of 422 mA h g −1 and a capacity retention of 379 mA h g −1 after 100 cycles.

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