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Oxidative Coupling Reactions of Grignard Reagents with Nitrous Oxide
Author(s) -
Kiefer Gregor,
Jeanbourquin Loïc,
Severin Kay
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302471
Subject(s) - inert , nitrous oxide , grignard reagent , catalysis , reagent , grignard reaction , chemistry , combinatorial chemistry , computer science , database , organic chemistry
Catalysis with laughing gas : N 2 O in combination with transition‐metal catalysts allow the oxidative homo‐ and cross‐coupling of Grignard reagents. The reactions can be performed under mild conditions despite the inert character of N 2 O.
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