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SiSi and SiO Bond Activation at Platinum: Stepwise Formation of a SiH 3 Complex
Author(s) -
Mitzenheim Cathérine,
Braun Thomas
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302459
Subject(s) - silane , silylation , platinum , stoichiometry , chemistry , silanes , silicon , medicinal chemistry , inorganic chemistry , catalysis , organic chemistry
The more, the better : Treatment of [Pt(H) 2 (dcpe)] (dcpe=1,2‐bis(dicyclohexylphosphino)ethane) with stoichiometric amounts of silane leads to the bis(silyl) complex [Pt{Si(OMe) 3 } 2 (dcpe)], whereas the use of an excess silane results in hydrodealkoxylations by repetitive SiO bond activation and the formation of SiH 3 ligands (see scheme; Cy=cyclohexyl).
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