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Synthesis of (+)‐Schisanwilsonene A by Tandem Gold‐Catalyzed Cyclization/1,5‐Migration/Cyclopropanation
Author(s) -
Gaydou Morgane,
Miller Ricarda E.,
Delpont Nicolas,
Ceccon Julien,
Echavarren Antonio M.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302411
Subject(s) - cyclopropanation , tandem , key (lock) , service (business) , computer science , combinatorial chemistry , chemistry , information retrieval , world wide web , catalysis , business , organic chemistry , engineering , computer security , aerospace engineering , marketing
Going (anti)viral : The first total synthesis of the antiviral (+)‐schisanwilsonene A has been completed using a fully stereoselective tandem cyclization/1,5‐migration/intermolecular cyclopropanation. The key reaction sequence is catalyzed by gold.