Premium
A Response to the Critical Comments on “One Molecule, Two Atoms, Three Views, Four Bonds?”
Author(s) -
Danovich David,
Shaik Sason,
Rzepa Henry S.,
Hoffmann Roald
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302350
Subject(s) - bond , criticism , molecule , chemical bond , gauge (firearms) , computational chemistry , chemistry , theoretical physics , epistemology , philosophy , materials science , physics , law , organic chemistry , political science , economics , finance , metallurgy
The criticism expressed by Frenking and Hermann on the notion of quadruple bonding in C 2 is answered using hard facts. Both experimental and computational data gauge the strength of the fourth bond as 16 kcal mol −1 . The authors agree that chemical research goes profitably beyond “synthetic” chemistry.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom