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Domino Cycloaddition Organocascades of Dendralenes
Author(s) -
Green Nicholas J.,
Lawrence Andrew L.,
Bojase Gomotsang,
Willis Anthony C.,
PaddonRow Michael N.,
Sherburn Michael S.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302185
Subject(s) - domino , cycloaddition , computer science , programming language , biology , catalysis , biochemistry
Hooray Horeau! Highly enantioselective organocatalyzed Diels–Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes.