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Back Cover: Recyclable Mitsunobu Reagents: Catalytic Mitsunobu Reactions with an Iron Catalyst and Atmospheric Oxygen (Angew. Chem. Int. Ed. 17/2013)
Author(s) -
Hirose Daisuke,
Taniguchi Tsuyoshi,
Ishibashi Hiroyuki
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302117
Subject(s) - reagent , mitsunobu reaction , catalysis , hydrazine (antidepressant) , chemistry , phthalocyanine , atmospheric oxygen , combinatorial chemistry , organic chemistry , polymer chemistry , oxygen , chromatography
Ethyl 2‐arylhydrazinecarboxylates , which are aerobically oxidized by iron catalysis into the corresponding azo species, can act as recyclable reagents in the Mitsunobu reaction. In their Communication on page 4613 ff., Taniguchi et al. report Mitsunobu reactions using catalytic amounts of these hydrazine reagents and iron phthalocyanine in the presence of air.