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Through‐Space Electronic Energy Transfer Across Proximal Molecular Dyads
Author(s) -
Harriman Anthony,
Alamiry Mohammed A. H.,
Hagon Jerry P.,
Hablot Delphine,
Ziessel Raymond
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201302081
Subject(s) - space (punctuation) , ideal (ethics) , dipole , transfer (computing) , information transfer , computer science , energy transfer , energy (signal processing) , physics , information retrieval , quantum mechanics , atomic physics , telecommunications , philosophy , epistemology , parallel computing , operating system
Energy transfer : For large electronic systems in close proximity it is shown that the coulombic mechanism accounts for the rates of electronic energy transfer for both linear and perpendicular geometries across distances from 36 to 16 Å. Replacing the ideal dipole approximation with either a revised extended dipole or atom‐localized charges improves agreement between theory and experiment.