Noncovalent Interactions in Organocatalysis: Modulating Conformational Diversity and Reactivity in the MacMillan Catalyst | Zendy

Holland Mareike C. | Zendy; Paul Shyeni | Zendy; Schweizer W. Bernd | Zendy; Bergander Klaus | Zendy; MückLichtenfeld Christian | Zendy; Lakhdar Sami | Zendy; Mayr Herbert | Zendy; Gilmour Ryan | Zendy

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Noncovalent Interactions in Organocatalysis: Modulating Conformational Diversity and Reactivity in the MacMillan Catalyst

Author(s) -

Holland Mareike C.,

Paul Shyeni,

Schweizer W. Bernd,

Bergander Klaus,

MückLichtenfeld Christian,

Lakhdar Sami,

Mayr Herbert,

Gilmour Ryan

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301864

Subject(s) - reactivity (psychology) , catalysis , non covalent interactions , organocatalysis , chemistry , diversity (politics) , posttranslational modification , stereochemistry , molecule , biochemistry , organic chemistry , political science , hydrogen bond , enzyme , medicine , alternative medicine , pathology , enantioselective synthesis , law

Intriguing imidazolidinones! Inspired by noncovalent interactions in proteins, a series of electronically distinct MacMillan catalysts were designed. The effect of electronic modulation on ground state conformation, reactivity, and performance was studied in a catalytic setting with intriguing outcomes.

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