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Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex
Author(s) -
Krafft Michael J.,
Bubrin Martina,
Paretzki Alexa,
Lissner Falk,
Fiedler Jan,
Záliš Stanislav,
Kaim Wolfgang
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201301706
Subject(s) - hydride , ferrocene , steric effects , chemistry , hydrogen , computer science , combinatorial chemistry , information retrieval , service (business) , electron transfer , cobalt , stereochemistry , photochemistry , business , organic chemistry , electrochemistry , electrode , marketing
Step by step : Electron‐ and hydrogen‐transfer steps are documented IR‐spectroelectrochemically and structurally for the H 2 ‐producing oxidation of a dicarbonylcobalt hydride complex modified by the sterically protecting 1,1′‐bis(diisopropylphosphino)ferrocene. The series complements the mechanism discussed for water‐reducing cobalt compounds with less π‐accepting ligands.