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Catalytic Regioselective Oxidation of Glycosides
Author(s) -
Jäger Manuel,
Hartmann Marcel,
de Vries Johannes G.,
Minnaard Adriaan J.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201301662
Subject(s) - monosaccharide , glycoside , regioselectivity , chemistry , catalysis , organic chemistry
Discrimination among equals : A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting‐group‐free synthetic transformations of carbohydrates.
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