Inside Cover: Oxidative Cyclodimerization After Tandem Cyclization of Dehydrobenzo[14]annulenes Induced by Alkyllithium (Angew. Chem. Int. Ed. 15/2013) | Zendy

Nobusue Shunpei | Zendy; Shimizu Akihiro | Zendy; Hori Kenji | Zendy; Hisaki Ichiro | Zendy; Miyata Mikiji | Zendy; Tobe Yoshito | Zendy

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Inside Cover: Oxidative Cyclodimerization After Tandem Cyclization of Dehydrobenzo[14]annulenes Induced by Alkyllithium (Angew. Chem. Int. Ed. 15/2013)

Author(s) -

Nobusue Shunpei,

Shimizu Akihiro,

Hori Kenji,

Hisaki Ichiro,

Miyata Mikiji,

Tobe Yoshito

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301655

Subject(s) - annulene , chemistry , ring (chemistry) , tandem , cover (algebra) , medicinal chemistry , oxidative phosphorylation , combinatorial chemistry , stereochemistry , photochemistry , organic chemistry , materials science , engineering , composite material , mechanical engineering , biochemistry

Transannular cyclization of dehydrobenzoannulenes is a powerful method to construct new carbon frameworks that are otherwise difficult to achieve. In their Communication on page 4184 ff. , Y. Tobe and co‐workers show that the reaction of dehydrobenzo[14]annulenes with n ‐butyllithium leads to an unprecedented oxidative cyclodimerization to form eight‐membered‐ring products, following threefold transannular bond formations across a 14‐membered ring.

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