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Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β‐Hydroxysulfones
Author(s) -
Lu Qingquan,
Zhang Jian,
Wei Fuliang,
Qi Yue,
Wang Huamin,
Liu Zhiliang,
Lei Aiwen
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201301634
Subject(s) - chemistry , tertiary care , alkene , transition metal , combinatorial chemistry , organic chemistry , catalysis , medicine , family medicine
New channel! A novel and attractive dioxygen activation by sulfinic acids was explored that is capable of performing efficiently without the assistance of transition metals or radical initiators. This reaction furnishes secondary and tertiary β‐hydroxysulfones under mild conditions; β‐hydroperoxysulfone was isolated as an important intermediate.