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Zinc‐Catalyzed Synthesis of Functionalized Furans and Triarylmethanes from Enynones and Alcohols or Azoles: Dual XH Bond Activation by Zinc
Author(s) -
González Jesús,
González Javier,
PérezCalleja Carmela,
López Luis A.,
Vicente Rubén
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201301625
Subject(s) - chemistry , zinc , catalysis , organic chemistry , dual role , combinatorial chemistry , medicinal chemistry
Ba'zinc'ga! A zinc‐catalyzed sequence involving a cyclization with a subsequent CO, CN, or CC bond formation enables the preparation of a variety of valuable furfuryl ethers (with alcohols) and unsymmetrically substituted triarylmethane derivatives (with azoles or arenes). ZnCl 2 serves as the catalyst.