Synthesis and Complexes of Fluoroalkoxy Carbenes | Zendy

Arduengo Anthony J. | Zendy; Dolphin Joshua S. | Zendy; Gurău Gabriela | Zendy; Marshall William J. | Zendy; Nelson Joseph C. | Zendy; Petrov Viacheslav A. | Zendy; Runyon Jason W. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis and Complexes of Fluoroalkoxy Carbenes

Author(s) -

Arduengo Anthony J.,

Dolphin Joshua S.,

Gurău Gabriela,

Marshall William J.,

Nelson Joseph C.,

Petrov Viacheslav A.,

Runyon Jason W.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301503

Subject(s) - deprotonation , computer science , alkylation , combinatorial chemistry , service (business) , chemistry , world wide web , information retrieval , organic chemistry , business , catalysis , ion , marketing

Gripping ligands : A series of fluoroalkoxy‐functionalized imidazol‐2‐ylidene ligands were synthesized by the alkylation of a range of commercially available azoles with hexafluoroisobutylene oxide. The deprotonation of these species with a strong base cleanly generated the free carbenes, which acted as tridentate chelating ligands (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research