Silicon(II) Coordination Chemistry: N‐Heterocyclic Carbene Complexes of Si 2+  and SiI + | Zendy

Filippou Alexander C. | Zendy; Lebedev Yury N. | Zendy; Chernov Oleg | Zendy; Straßmann Martin | Zendy; Schnakenburg Gregor | Zendy

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Silicon(II) Coordination Chemistry: N‐Heterocyclic Carbene Complexes of Si 2+ and SiI +

Author(s) -

Filippou Alexander C.,

Lebedev Yury N.,

Chernov Oleg,

Straßmann Martin,

Schnakenburg Gregor

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301363

Subject(s) - carbene , adduct , swap (finance) , chemistry , ligand (biochemistry) , stereochemistry , medicinal chemistry , organic chemistry , catalysis , finance , economics , biochemistry , receptor

Ligand swap : The exchange of N‐heterocyclic carbene (NHC) ligands at Si II centers is shown to provide access to a dicationic NHC complex of silicon(II), and an NHC adduct of the iodosilyliumylidene cation SiI + , [SiI(I i Pr 2 Me 2 )(IDipp)] + (see picture). Characterization studies led to the discovery of an unprecedented CH⋅⋅⋅Si anagostic interaction for [SiI(I i Pr 2 Me 2 )(IDipp)] + .

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