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Mild Rhodium(III)‐Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates
Author(s) -
Wang Honggen,
Schröder Nils,
Glorius Frank
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201301165
Subject(s) - rhodium , catalysis , chemistry , combinatorial chemistry , scope (computer science) , intermolecular force , selectivity , medicinal chemistry , computer science , organic chemistry , molecule , programming language
All(yl) possible! A rhodium(III)‐catalyzed intermolecular direct CH allylation reaction utilizing readily accessible allyl carbonates was developed. This method allows the allylation of electron‐neutral arenes, providing complete γ‐selectivity, high isomeric ratio, good substrate scope, and excellent functional group compatibility.