Unveiling Latent α‐Iminocarbene Reactivity for Intermolecular Cascade Reactions through Alkyne Oxidative Amination | Zendy

Mace Nina | Zendy; Thornton Aaron R. | Zendy; Blakey Simon B. | Zendy

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Unveiling Latent α‐Iminocarbene Reactivity for Intermolecular Cascade Reactions through Alkyne Oxidative Amination

Author(s) -

Mace Nina,

Thornton Aaron R.,

Blakey Simon B.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301087

Subject(s) - alkyne , intermolecular force , reactivity (psychology) , cascade , amination , chemistry , variety (cybernetics) , computer science , combinatorial chemistry , database , organic chemistry , molecule , catalysis , artificial intelligence , medicine , alternative medicine , pathology , chromatography

Setting a trap : Described is the development of a metallonitrene‐initiated alkyne oxidation cascade with intermolecular trapping of the reactive intermediate with a variety of allyl ethers to provide α‐oxyimine products in which new CN, CO, and CC bonds have all been generated (see Scheme; tfacam=trifluoroacetamide).

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