Inside Cover: A Rare Uranyl(VI)–Alkyl Ate Complex [Li(DME) 1.5 ] 2 [UO 2 (CH 2 SiMe 3 ) 4 ] and Its Comparison with a Homoleptic Uranium(VI)–Hexaalkyl (Angew. Chem. Int. Ed. 11/2013) | Zendy

Seaman Lani A. | Zendy; Hrobárik Peter | Zendy; Schettini Michael F. | Zendy; Fortier Skye | Zendy; Kaupp Martin | Zendy; Hayton Trevor W. | Zendy

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Inside Cover: A Rare Uranyl(VI)–Alkyl Ate Complex [Li(DME) 1.5 ] 2 [UO 2 (CH 2 SiMe 3 ) 4 ] and Its Comparison with a Homoleptic Uranium(VI)–Hexaalkyl (Angew. Chem. Int. Ed. 11/2013)

Author(s) -

Seaman Lani A.,

Hrobárik Peter,

Schettini Michael F.,

Fortier Skye,

Kaupp Martin,

Hayton Trevor W.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301041

Subject(s) - homoleptic , uranyl , alkyl , chemistry , cover (algebra) , crystallography , methylene , medicinal chemistry , ion , metal , organic chemistry , mechanical engineering , engineering

A rare uranyl–alkyl “ate” complex was prepared for comparison with a homoleptic U VI –hexaalkyl. In their Communication on page 3259 ff., P. Hrobárik, T. Hayton, et al. demonstrate that both complexes feature unprecedented high‐frequency methylene 13 C shifts, consistent with large spin‐orbit effects. Relativistic calculations show that the cause is significant f‐orbital involvement in σ‐bonding.

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