Single‐Molecule Magnetism in a Single‐Ion Triamidoamine Uranium(V) Terminal Mono‐Oxo Complex | Zendy

King David M. | Zendy; Tuna Floriana | Zendy; McMaster Jonathan | Zendy; Lewis William | Zendy; Blake Alexander J. | Zendy; McInnes Eric J. L. | Zendy; Liddle Stephen T. | Zendy

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Single‐Molecule Magnetism in a Single‐Ion Triamidoamine Uranium(V) Terminal Mono‐Oxo Complex

Author(s) -

King David M.,

Tuna Floriana,

McMaster Jonathan,

Lewis William,

Blake Alexander J.,

McInnes Eric J. L.,

Liddle Stephen T.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201301007

Subject(s) - uranium , magnetism , anisotropy , molecule , uranium oxide , magnet , ion , chemistry , magnetic anisotropy , crystallography , materials science , magnetization , magnetic field , physics , condensed matter physics , metallurgy , organic chemistry , quantum mechanics

Single‐molecule magnets : Straightforward oxidation of a triamidoamine uranium(III) complex with trimethyl‐ N ‐oxide affords a uranium(V) terminal mono‐oxo complex which is the first clear‐cut example of a uranium(V) single‐molecule magnet (SMM). This monometallic complex unambiguously shows that a strongly axially ligated and thus anisotropic ligand field can be used to overcome the limited magnetic anisotropy of uranium(V).

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