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Synthesis of an Azahomoazafullerene C 59 N(NH)R and Gas‐Phase Formation of the Diazafullerene C 58 N 2
Author(s) -
Huang Huan,
Zhang Gaihong,
Wang Dian,
Xin Nana,
Liang Sisi,
Wang Nengdong,
Gan Liangbing
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300973
Subject(s) - moiety , gas phase , hydrolysis , mass spectrum , derivative (finance) , chemistry , singlet oxygen , oxygen , singlet state , medicinal chemistry , crystallography , stereochemistry , analytical chemistry (journal) , mass spectrometry , physics , organic chemistry , atomic physics , excited state , chromatography , financial economics , economics
Open the cage if you dare : The azahomoazafullerene 1 was prepared from a tert ‐butylperoxy‐substituted azafullerene derivative C 59 NBr(OO t Bu) 4 . Singlet oxygen added to 1 to form an open‐cage azafullerene 2 with a ketoimide moiety on the rim of the orifice. The MALDI‐TOF mass spectrum of the product of the hydrolysis of 1 showed a clear signal for the diazafullerene C 58 N 2 (see structure 3 ).
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