Synthesis and Application of β‐Substituted Pauson–Khand Adducts: Trifluoromethyl as a Removable Steering Group | Zendy

Aiguabella Nuria | Zendy; del Pozo Carlos | Zendy; Verdaguer Xavier | Zendy; Fustero Santos | Zendy; Riera Antoni | Zendy

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Synthesis and Application of β‐Substituted Pauson–Khand Adducts: Trifluoromethyl as a Removable Steering Group

Author(s) -

Aiguabella Nuria,

del Pozo Carlos,

Verdaguer Xavier,

Fustero Santos,

Riera Antoni

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300907

Subject(s) - trifluoromethyl , regioselectivity , intermolecular force , chemistry , adduct , alkyne , structural isomer , group (periodic table) , stereochemistry , medicinal chemistry , organic chemistry , molecule , catalysis , alkyl

Against the rules : The synthesis of the previously unknown β‐substituted regioisomers of the intermolecular Pauson–Khand reaction of terminal alkynes is reported. This regiochemistry was achieved by using the trifluoromethyl group as a removable directing group on the alkyne.

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