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Formation of Azaborines by Photoelimination of B,N‐Heterocyclic Compounds
Author(s) -
Lu JiaSheng,
Ko SooByung,
Walters Nicholas R.,
Kang Youngjin,
Sauriol Francoise,
Wang Suning
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300873
Subject(s) - conjugated system , computer science , unit (ring theory) , chemistry , service (business) , combinatorial chemistry , polymer , information retrieval , organic chemistry , mathematics , business , mathematics education , marketing
Highly fluorescent π‐conjugated polycyclic azaborines can be prepared from B,N‐heterocyclic compounds with a BR 2 ‐CH 2 unit through the elimination of an R‐H molecule (see scheme). These clean photoelimination reactions occur both in solution and in polymers doped with the precursors.