Premium
A High‐Valent Heterobimetallic [Cu III (μ‐O) 2 Ni III ] 2+ Core with Nucleophilic Oxo Groups
Author(s) -
Kundu Subrata,
Pfaff Florian Felix,
Miceli Enrico,
Zaharieva Ivelina,
Herwig Christian,
Yao Shenglai,
Farquhar Erik R.,
Kuhlmann Uwe,
Bill Eckhard,
Hildebrandt Peter,
Dau Holger,
Driess Matthias,
Limberg Christian,
Ray Kallol
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300861
Subject(s) - nucleophile , core (optical fiber) , chemistry , computer science , combinatorial chemistry , organic chemistry , catalysis , telecommunications
Cores and effect : Unlike homobimetallic analogues, the heterobimetallic CuNi bis(μ‐oxo) diamond core has nucleophilic oxo groups. A similar heterobimetallic core may, therefore, act as a viable intermediate during the deformylation of fatty aldehydes by cyanobacterial aldehyde decarbonylase.