Tandem Postsynthetic Modification of a Metal–Organic Framework by Thermal Elimination and Subsequent Bromination: Effects on Absorption Properties and Photoluminescence | Zendy

Sun Feng | Zendy; Yin Zheng | Zendy; Wang QueQiao | Zendy; Sun Di | Zendy; Zeng MingHua | Zendy; Kurmoo Mohamedally | Zendy

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Tandem Postsynthetic Modification of a Metal–Organic Framework by Thermal Elimination and Subsequent Bromination: Effects on Absorption Properties and Photoluminescence

Author(s) -

Sun Feng,

Yin Zheng,

Wang QueQiao,

Sun Di,

Zeng MingHua,

Kurmoo Mohamedally

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300821

Subject(s) - halogenation , tandem , sorption , surface modification , photoluminescence , absorption (acoustics) , chemistry , metal , solvent , inorganic chemistry , chemical engineering , organic chemistry , materials science , adsorption , optoelectronics , engineering , composite material

Inside and outside : Two consecutive postsynthetic modifications, first an elimination reaction in the channels and then bromination at the surface, were realized in a new hybrid metal–organic framework. The dramatic effects of the different groups in the channels and at the surface were studied using gas sorption and the loading/release of solvent and iodine.

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