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Tandem Postsynthetic Modification of a Metal–Organic Framework by Thermal Elimination and Subsequent Bromination: Effects on Absorption Properties and Photoluminescence
Author(s) -
Sun Feng,
Yin Zheng,
Wang QueQiao,
Sun Di,
Zeng MingHua,
Kurmoo Mohamedally
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300821
Subject(s) - halogenation , tandem , sorption , surface modification , photoluminescence , absorption (acoustics) , chemistry , metal , solvent , inorganic chemistry , chemical engineering , organic chemistry , materials science , adsorption , optoelectronics , engineering , composite material
Inside and outside : Two consecutive postsynthetic modifications, first an elimination reaction in the channels and then bromination at the surface, were realized in a new hybrid metal–organic framework. The dramatic effects of the different groups in the channels and at the surface were studied using gas sorption and the loading/release of solvent and iodine.