C 20 H 4 (C 4 F 8 ) 3 : A Fluorine‐Containing Annulated Corannulene that Is a Better Electron Acceptor Than C 60 | Zendy

Kuvychko Igor V. | Zendy; Dubceac Cristina | Zendy; Deng Shihu H. M. | Zendy; Wang XueBin | Zendy; Granovsky Alexander A. | Zendy; Popov Alexey A. | Zendy; Petrukhina Marina A. | Zendy; Strauss Steven H. | Zendy; Boltalina Olga V. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

C 20 H 4 (C 4 F 8 ) 3 : A Fluorine‐Containing Annulated Corannulene that Is a Better Electron Acceptor Than C 60

Author(s) -

Kuvychko Igor V.,

Dubceac Cristina,

Deng Shihu H. M.,

Wang XueBin,

Granovsky Alexander A.,

Popov Alexey A.,

Petrukhina Marina A.,

Strauss Steven H.,

Boltalina Olga V.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300796

Subject(s) - corannulene , x ray photoelectron spectroscopy , acceptor , chemistry , fullerene , physics , organic chemistry , nuclear magnetic resonance , condensed matter physics

At sixes and sevens : The reaction of corannulene with 35 equivalents of 1,4‐C 4 F 8 I 2 is an efficient and a relatively selective process that yields two main products in which six H atoms are substituted with three C 4 F 8 moieties that form six‐ and seven‐membered rings. Low‐temperature photoelectron spectroscopy showed the electron affinity of the major isomer (shown) exceeds that of C 60 (2.74±0.02 and 2.689±0.008 eV, respectively).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research