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Selective Palladium‐Catalyzed Hydroformylation of Alkynes to α,β‐Unsaturated Aldehydes
Author(s) -
Fang Xianjie,
Zhang Min,
Jackstell Ralf,
Beller Matthias
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300759
Subject(s) - hydroformylation , palladium , catalysis , stereoselectivity , chemistry , aldehyde , syngas , organic chemistry , alkyne , combinatorial chemistry , rhodium
Atom‐efficient : A selective palladium catalyst system is used for the hydroformylation of alkynes (see picture). In this syngas reaction, various alkynes were smoothly transformed to synthetically interesting α,β‐unsaturated aldehydes in good yields with high regio‐ and stereoselectivity.