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Organocatalyzed Carbonyl–Olefin Metathesis
Author(s) -
Lee AiLan
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300678
Subject(s) - olefin metathesis , reagent , metathesis , cycloaddition , catalysis , olefin fiber , chemistry , salt metathesis reaction , organic chemistry , combinatorial chemistry , polymer , polymerization
The heat is on : A new [3+2] cycloaddition/cycloreversion strategy allows for catalytic and thermally allowed carbonyl–olefin metathesis (see scheme). This strategy opens opportunities for new developments in the field of carbonyl–olefin metathesis, which traditionally relied on stoichiometric amounts of transition‐metal reagents or photochemical promotion.