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Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks
Author(s) -
Kang Narae,
Park Ji Hoon,
Ko Kyoung Chul,
Chun Jiseul,
Kim Eunchul,
Shin HeeWon,
Lee Sang Moon,
Kim Hae Jin,
Ahn Tae Kyu,
Lee Jin Yong,
Son Seung Uk
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201300655
Subject(s) - tandem , microporous material , sonogashira coupling , photocatalysis , hydroquinone , intramolecular force , chemistry , oxidative coupling of methane , combinatorial chemistry , photochemistry , organic chemistry , materials science , catalysis , palladium , composite material
Tiny pores : Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5‐triethynylbenzene and 2,5‐diiodo‐1,4‐hydroquinone and intramolecular cyclization. The resultant benzodifuran‐containing MON showed promising photocatalytic activities in the oxidative conversion of primary amines into imines.