Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium‐ion‐like Surface Species | Zendy

Ahrens Mike | Zendy; Scholz Gudrun | Zendy; Braun Thomas | Zendy; Kemnitz Erhard | Zendy

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Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium‐ion‐like Surface Species

Author(s) -

Ahrens Mike,

Scholz Gudrun,

Braun Thomas,

Kemnitz Erhard

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201300608

Subject(s) - chemistry , catalysis , cleavage (geology) , ion , bond cleavage , friedel–crafts reaction , aluminium , inorganic chemistry , photochemistry , polymer chemistry , medicinal chemistry , organic chemistry , materials science , composite material , fracture (geology)

'Al'l about F : Aluminum chlorofluoride (ACF) catalyzes the hydrodefluorination, as well as Friedel–Crafts reactions of fluorinated methanes in the presence of Et 3 SiH. A surface‐bound silylium‐ion‐like species is considered to be a crucial intermediate in achieving the CF bond cleavage.

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